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Paper, vegetables, polypropylene wastes

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TI NJAUAN PUSTAKA
1. Paper waste : pemanfaatan, kandungan
Kumar et al., (2020) reported that waste paper contains high cellulose (60–70%),
which is higher than any other raw materials summarized previously with hemicelluloses
(10–20%) and lignin (5–10%). Such a composition makes it an ideal material for
isolation of nanocellulose (Lee et al., 2014a). Recovered paper, refused paper, scrap
paper, secondary paper, discarded paper, used paper and paper stock frequently
represented the waste paper. With increased production of paper, a huge amount of waste
paper (more than 400 million tons) is generated annually (Shi et al., 2009). Since the
decade of 1970s, interest has been developed for recovery and recycling of waste paper to
reduce the global environmental problems like carbon dioxide emission, high energy &
chemical demand, deforestation and destruction of natural resources. The worldwide
collection or recovery of waste paper has been increased between the year 1970 (31
million tons) and 2010 (210 million tons) (Mansikkasalo et al., 2014, FAO, 2015,
Laurijssen et al., 2010). The global consumption of waste paper was 213 million tons in
2011 and 235 million tons in 2018 (FAO, 2018). In 2015, the world business council for
sustainable development reported the recovery of paper and paperboard in developed
countries nearing to 70% in the USA, over 70% in Europe, and nearly 80% in Japan
(State of The Global Paper Industry 2018 - Report). The recycling rate of waste paper at
global level is around 57.9% with (85%) in Australia, 72% in Europe, 70% Canada, 64%
United States and 61% in South Africa (FAO, 2018, State of The Global Paper Industry
2018 - Report).
2. Vegetable Waste : pemanfaatan, kandungan
Chua et al., (2019) reported that food wastes were collected randomly from the
university’s café, Indian and Chinese restaurants, morning and night markets, and also
from a household. It was then sorted, weighed, crushed and blended before further
characterization. Food wastes from university’s café were then hydrothermal pre-treated
at 120C for 75 min at a food waste to water ratio of 1:2. Total solid and volatile solid
contents and moisture content of various untreated and pretreated food wastes were
analyzed by Standard Method, while the composition of lipid was determined by Bligh &
Dyer method. Protein and carbohydrate contents were determined by Bradford method
and Phenol-sulphuric Acid method, respectively. These wastes were further characterized
for their moisture, TS, VS, carbohydrate, protein and lipid contents.
Since protein-containing food like chicken and meat are normally smaller in
amount and more expensive in a meal, they tend to finish it and left behind carbohydratecontaining food like rice and noodles. As a result, the composition of the waste collected
is higher in carbohydrate. This corresponds to the results obtained for nutrients analysis
in Fig. 1(b). Pre-processing wastes are mainly vegetables and fruits that contain a high
amount of cellulose fibers. Hence, these wastes are solely complex carbohydrate. As
such, food waste hydrolysate after hydrothermal pretreatment of solid food wastes has a
higher content of carbohydrate, protein, and lipid
3. Plastic polypropylene (PP) waste: pemanfaatan, kandungan
Ciri-ciri plastik jenis ini biasanya transparan tetapi tidak jernih atau berawan,
keras tetapi fleksibel, kuat, permukaan berlilin, tahan terhadap bahan kimia, panas dan
minyak, melunak pada suhu 140°C (Arif, 2018). Kurniawan & Yulianto (2020)
melaporkan bahwav polypropylene merupakan salah satu jenis termoplastik. Plastik jenis
ini bisa digunakan untuk perekat termoplastik dalam pengolahan papan partikel.
Polypropylene masuk kedalam jenis plastik olefin dan polymer dari propylene. Diantara
material plastik lainnya, PP (Polypropylene) memiliki kerapatan yang paling rendah,
yaitu berkisar antara 0.855-0,946 gr/cm3 serta titik leleh yang tinggi (165 – 170 °C)
sedangkan HDPE (high density polyethylene) memiliki kerapatan 0,941- 0,970 gr/cm3
serta titik leleh (127-135°C) dan kerapatan LDPE (low density polyethylene) 0,910-0,940
gr/cm3 serta titik leleh 115°C. Polypropylene merupakan jenis plastik yang dapat di daur
ulang sehingga memiliki potensi sebagai matriks dalam pembuatan komposit papan
partikel. Melihat sifat plastik yang tidak mudah terurai secara biologis dapat
menyebabkan dampak buruk bagi lingkungan,cara terbaik yaitu memanfaatkannya
menjadi produk lain. Pada pembuatan papan partikel komposit, ukuran partikel juga
mempengaruhi terhadap kekuatan papan komposit jika ukuran partikel seragam maka
bahan penyusun papan komposit akan saling mengikat dan menghasilkan kualitas papan
partikel yang jauh lebih baik.
Jun & Juwono (2010) melaporkan bahwa identifikasi dengan Fourier Transform
Infrared (FTIR) menunjukkan bahwa PP daur ulang komersial mengandung campuran
unsur polyethylene (PE) yang tidak terdapat pada PP murni dan PP daur ulang. Hasil uji
tarik dan uji kekerasan menunjukkan tidak ada perubahan yang signifikan antara PP
murni dan PP daur ulang. Di sisi lain, hasil uji tarik PP daur ulang menunjukkan bahwa
kuat tarik lebih rendah 22,1% daripada PP murni, modulus Young turun 8,1%, dan strainat-break berkurang secara drastis sebesar 65,7%. Uji kekerasan pada PP daur ulang
komersial menunjukkan bahwa kekerasan relatif tidak berubah. Pengamatan permukaan
dengan Scanning Electron Microscope (SEM) memperlihatkan PP daur ulang komersial
memiliki permukaan yang relatif lebih datar dengan ukuran butir lebih kecil
dibandingkan dengan permukaan PP murni, yang menunjukkan bahwa bahan PP daur
ulang komersial lebih brittle dibandingkan PP daur ulang. Hasil ini mendukung hasil uji
tarik dimana terjadi penurunan signifikan pada strain-at-break PP daur ulang komersial.
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